全文获取类型
收费全文 | 352篇 |
免费 | 7篇 |
国内免费 | 66篇 |
专业分类
安全科学 | 7篇 |
废物处理 | 5篇 |
环保管理 | 64篇 |
综合类 | 170篇 |
基础理论 | 65篇 |
污染及防治 | 84篇 |
评价与监测 | 23篇 |
社会与环境 | 7篇 |
出版年
2023年 | 5篇 |
2022年 | 7篇 |
2021年 | 9篇 |
2020年 | 10篇 |
2019年 | 9篇 |
2018年 | 10篇 |
2017年 | 10篇 |
2016年 | 14篇 |
2015年 | 20篇 |
2014年 | 22篇 |
2013年 | 23篇 |
2012年 | 11篇 |
2011年 | 46篇 |
2010年 | 20篇 |
2009年 | 21篇 |
2008年 | 29篇 |
2007年 | 19篇 |
2006年 | 20篇 |
2005年 | 12篇 |
2004年 | 8篇 |
2003年 | 20篇 |
2002年 | 18篇 |
2001年 | 10篇 |
2000年 | 5篇 |
1999年 | 9篇 |
1998年 | 5篇 |
1997年 | 6篇 |
1996年 | 4篇 |
1995年 | 2篇 |
1994年 | 3篇 |
1993年 | 1篇 |
1992年 | 7篇 |
1991年 | 3篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1982年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有425条查询结果,搜索用时 296 毫秒
1.
The methodology of materials accounting is presented and applied to developing nutrient balance (nitrogen and phosphorus)
in a river basin. The method is based on the balance principle: inputs and outputs of each nitrogen and phosphorus related
sub-systems were balanced. The application of the methodology strategies was illustrated by means of a case study of the Krka
river, Slovenia. Different pathways of emission to surface waters were taken into account: WWTP discharges, direct discharges,
erosion/runoff and baseflow. Total annual emission into the river Krka was estimated to be 362 tonnes N/year and 73.3 tonnes
P/year. The main sources of nitrogen are diffuse sources, emitted via baseflow (52%). Other important sources are effluents
from WWTP, which account for 36% of total emissions. Other sources like erosion and direct discharges to surface water (animal
manure, industry, households) are of lower magnitude. Erosion is main source of phosphorus emission (55% of total emission),
WWTP effluents account for 37% of total emission, while other sources are less important. Besides reduction of point sources
by means of wastewater collection and implementation of nutrient removal technology, managing agricultural nitrogen and phosphorus
to protect water quality should become a major challenge in the Krka river basin. 相似文献
2.
Controls on Nutrients Across a Prairie Stream Watershed: Land Use and Riparian Cover Effects 总被引:1,自引:0,他引:1
Nutrient inputs generally are increased by human-induced land use changes and can lead to eutrophication and impairment of
surface waters. Understanding the scale at which land use influences nutrient loading is necessary for the development of
management practices and policies that improve water quality. The authors assessed the relationships between land use and
stream nutrients in a prairie watershed dominated by intermittent stream flow in the first-order higher elevation reaches.
Total nitrogen, nitrate, and phosphorus concentrations were greater in tributaries occupying the lower portions of the watershed,
closely mirroring the increased density of row crop agriculture from headwaters to lower-elevation alluvial areas. Land cover
classified at three spatial scales in each sub-basin above sampling sites (riparian in the entire catchment, catchment land
cover, and riparian across the 2 km upstream) was highly correlated with variation in both total nitrogen (r2 = 53%, 52%, and 49%, respectively) and nitrate (r2 = 69%, 65%, and 56%, respectively) concentrations among sites. However, phosphorus concentrations were not significantly
associated with riparian or catchment land cover classes at any spatial scale. Separating land use from riparian cover in
the entire watershed was difficult, but riparian cover was most closely correlated with in-stream nutrient concentrations.
By controlling for land cover, a significant correlation of riparian cover for the 2 km above the sampling site with in-stream
nutrient concentrations could be established. Surprisingly, land use in the entire watershed, including small intermittent
streams, had a large influence on average downstream water quality although the headwater streams were not flowing for a substantial
portion of the year. This suggests that nutrient criteria may not be met only by managing permanently flowing streams. 相似文献
3.
The use of a phosphorus amendment in altering Pb to a chemically less mobile phase is a promising strategy based on minimizing ecotoxicological risk and improving time and cost efficiency. This study evaluated crystalline and poorly-crystalline hydroxyapatite sorbents on removal of aqueous Pb in response to reaction time, solution pH, and Pb concentration. Batch experiments were conducted using a commercially-available crystalline hydroxyapatite (HA), and two poorly-crystalline hydroxyapatites synthesized from gypsum waste (CHA) and incinerated ash of poultry waste (MHA). Poorly-crystalline hydroxyapatites had greater capacity for Pb removal from a solution with a wider pH range as compared to a crystalline hydroxyapatite. The maximum sorption capacity of Pb determined by the Langmuir model was 500 mg g−1 for CHA, 277 mg g−1 for MHA and 145 mg g−1 for HA. Removal of aqueous Pb by CHA was not dependent on solution pH, with a 98.8% reduction throughout the solution pH range of 2–9, whereas aqueous Pb removal by HA and MHA was pH-dependent with less removal in the neutral solution pH. Poorly-crystalline hydroxyapatites may provide an effective alternative to existing remediation technologies for Pb-contaminated sites. 相似文献
4.
Influence of environmental factors on arsenic accumulation and biotransformation using the aquatic plant species Hydrilla verticillata 总被引:1,自引:0,他引:1
Hydrilla verticillata(waterthyme) has been successfully used for phytoremediation in arsenic(As) contaminated water.To evaluate the effects of environmental factors on phytoremediation,this study conducted a series of orthogonal design experiments to determine optimal conditions,including phosphorus(P),nitrogen(N),and arsenate(As(Ⅴ))concentrations and initial pH levels,for As accumulation and biotransformation using this aquatic plant species,while also analyzing As species transformation in culture media after 96-hr exposure.Analysis of variance and the signal-to-noise ratio were used to identify both the effects of these environmental factors and their optimal conditions for this purpose.Results indicated that both N and P significantly impacted accumulation,and N was essential in As species transformation.High N and intermediate P levels were critical to As accumulation and biotransformation by H.verticillata,while high N and low P levels were beneficial to As species transformation in culture media.The highest total arsenic accumulation was(197.2±17.4) μg/g dry weight when As(V) was at level 3(375μg/L),N at level 2(4 mg/L),P at level 1(0.02 mg/L),and pH at level 2(7).Although H.verticillata is highly efficient in removing As(Ⅴ) from aquatic environments,its use could be potentially harmful to both humans and the natural environment due to its release of highly toxic arsenite.For cost-effective and ecofriendly phytoremediation of As-contaminated water,both N and P are helpful in regulating As accumulation and transformation in plants. 相似文献
5.
Juan Huang Jun Xiao Yang Guo Wenzu Guan Chong Cao Chunni Yan Mingyu Wang 《环境科学学报(英文版)》2020,32(1):319-330
Silver nanoparticles(AgNPs) have been widely used in many fields,which raised concerns about potential threats to biological sewage treatment systems.In this study,the phosphorus removal performance,enzymatic activity and microbial population dynamics in constructed wetlands(CWs) were evaluated under a long-term exposure to Ag NPs(0,50,and 200 μg/L) for 450 days.Results have shown that Ag NPs inhibited the phosphorus removal efficiency in a short-term exposure,whereas caused no obviously negative effects from a long-term perspective.Moreover,in the coexisting CW system of Ag NPs and phosphorus,competition exhibited in the initial exposure phase,however,cooperation between them was observed in later phase.Enzymatic activity of acid-phosphatase at the moderate temperature(10–20°C) was visibly higher than that at the high temperature(20–30℃) and CWs with Ag NPs addition had no appreciable differences compared with the control.High-throughput sequencing results indicated that the microbial richness,diversity and composition of CWs were distinctly affected with the extension of exposure time at different Ag NPs levels.However,the phosphorus removal performance of CWs did not decline with the decrease of polyphosphate accumulating organisms(PAOs),which also confirmed that adsorption precipitation was the main way of phosphorus removal in CWs.The study suggested that Ag NPs and phosphorus could be removed synergistically in the coexistence system.This work has some reference for evaluating the influences of Ag NPs on the phosphorus removal and the interrelation between them in CWs. 相似文献
6.
利用分级提取法分析了玄武湖的沉积磷形态,在玄武湖沉积物中,铝结合态磷的含量较低,平均值为64 mg/kg,其余形态磷中,铁结合态磷为241 mg/kg,有机磷为335 mg/kg,钙结合态磷为394 mg/kg.在环境变化的条件下,铁结合态磷可以释放到间隙水和上层水体中,是湖泊产生富营养化的重要因素;铝结合态磷由于含量少,对湖泊富营养化影响很小;钙结合态磷相对稳定且很难被生物利用,对湖泊富营养化影响不大;有机磷对水体有机负荷影响较大,并影响水体富营养化程度. 相似文献
7.
8.
9.
本试验以HAc作为厌氧释磷的碳源有机物,以SBR系统外循环污泥作为研究对象,探索外循环活性污泥的厌氧释磷能力和获取高浓度富磷污水的途径,试验表明:厌氧过程中聚磷菌吸收HAc和释放PO4^3 的分子比为1:1。即吸收2.06mgHAc-COD将诱导1mgP释放,单位时段比污泥的平均释磷速率Vp=6.54.t^0.76,理想的厌氧时间为60-180min,减少循环污泥释磷系统的反应容积可以提高富磷污水磷酸盐的浓度。 相似文献
10.
反硝化聚磷一体化设备生产性实验研究 总被引:4,自引:0,他引:4
反硝化聚磷一体化设备主要特点是在利用含反硝化聚磷菌的活性污泥在缺氧状态过量聚磷,在完成磷去除的同时进行反硝化。通过实验得出缺氧释磷在前30min内大量释放,60min以后甚微;反硝化吸磷在最初10几分钟内速率极大;吸磷与反硝化紧密相关;聚磷菌在释、聚磷时利用一定量的有机物。 相似文献